IUBMB Enzyme Nomenclature

EC 2.3.1.334

Accepted name: cocaine synthase

Reaction: benzoyl-CoA + ecgonine methyl ester = CoA + cocaine

For diagram of reaction click here.

Systematic name: benzoyl-CoA:ecgonine methyl ester O-benzoyltransferase

Comments: Isolated from the plant Erythoxylum coca. Cinnamoyl-CoA can substitute for benzoyl-CoA.

Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number:

References:

1. Schmidt, G.W., Jirschitzka, J., Porta, T., Reichelt, M., Luck, K., Torre, J.C., Dolke, F., Varesio, E., Hopfgartner, G., Gershenzon, J. and D'Auria, J.C. The last step in cocaine biosynthesis is catalyzed by a BAHD acyltransferase. Plant Physiol. 167 (2015) 89-101. [PMID: 25406120]

[EC 2.3.1.334 created 2025]


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