Mechanism for EC 4.1.99.24 L-tyrosine isonitrile synthase

and EC 4.1.99.25 L-tryptophan isonitrile synthase

Mechanism suggested by Chang, W.C., Sanyal, D., Huang, J.L., Ittiamornkul, K., Zhu, Q. and Liu, X. In vitro stepwise reconstitution of amino acid derived vinyl isocyanide biosynthesis: detection of an elusive intermediate. Org. Lett. 19 (2017) 1208–1211. [PMID: 28212039]

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EC 4.1.99.24 L-tyrosine isonitrile synthase
EC 4.1.99.25 L-tryptophan isonitrile synthase